How do I make the profile pic bigger like yours? mine is 48x48 wich is the maximum size, but is still smaller
You should be able to just edit this one without submitting a new one.
On PJ, you're encouraged to use a transparent background rather than a solid filler colour, unless the solid background somehow improves the piece (see rule 4 on the submission page). I personally think this would be better with a transparent background. If you really like the green, maybe you should expand it into a background that's more than just a solid colour.
Where did you get the 48x48 limit from? Unless it was changed recently, the limit is larger than that (64x64 I think).
If you mean the file size - make sure it's in indexed mode rather than RGB, makes for much smaller files.