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As FreshSheet says, the face shading looks odd. That's because you lose the sense of his face being round. It's hard to describe however, and for the sake of not confusing you I'll just leave it to you to figure out how to fix it.
I think you went a bit too overboard with anti-aliasing. I've also sever seen anyone's face shaded like that. I guess it's not wrong but it looks weird to me.
I like the design of it a lot.
I think it's the lack of a neck that makes the head look a bit strange. The shape itself looks OK to me. relative to this site, it's not very little. =p